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Congratulations to Oleg Khazipov and autors!The article has been published in Organic Chemistry Frontiers!

2021-04-05 16:14
Nickel is about 5,000 times cheaper than palladium so its compounds are considered as an alternative to expensive Pd-catalysts. However generating of catalytically active forms of Ni(0) frequently is a serios problem. Therefore expensive and highly air-unstable compounds of zerovalent Nickel such as Ni(COD)2 are usually used as catalysts. Our new article published in Organic Chemistry Frontiers described a new simple method for the generation of active Ni(0)/NHC systems from a stable industrial reagent - nickelocene and safe sodium formate, as well as using of these systems in catalysis of CH-activation reactions DOI LINK